PREPARATION OF NEW LITHIUM ORGANOTRIHYDROALUMINATES - CRYSTAL-STRUCTURE OF ((C4H8O)(2)LI(MU-H)(2)ALH[C(SIME(2)PH)(3)])(2)

被引：38

作者：

EABORN, C

GORRELL, IB

HITCHCOCK, PB

SMITH, JD

TAVAKKOLI, K

机构：

[1] School of Chemistry and Molecular Sciences, University of Sussex, Falmer

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 11期

关键词：

D O I：

10.1021/om00023a007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of RLi (R = (Me(3)Si)(3)C or (Me(2)-PhSi)(3)C) with Li[AlH4] in tetrahydrofuran. (THF) gives the new stable alkyltrihydroaluminates Li[AlRH(3)].2THF, which are dimeric both in the solid state and in solution and are important starting materials for the synthesis of a range of organoaluminum compounds bearing bulky substituents.

引用

页码：4143 / 4144

页数：2

共 21 条

[1] A STABLE CARBENE ALANE ADDUCT
ARDUENGO, AJ
DIAS, HVR
CALABRESE, JC
DAVIDSON, F
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (24) : 9724 - 9725
[2] CONCERNING REACTIONS OF LITHIUM AND SODIUM ALUMINUM-HYDRIDE WITH GRIGNARD-REAGENTS IN ETHER SOLVENTS
ASHBY, EC
SCHWARTZ, RD
[J]. INORGANIC CHEMISTRY, 1972, 11 (05) : 919 - &
[3] AN ELECTRON-DEFICIENT INDIUM HYDRIDE - CRYSTAL-STRUCTURE AND NMR-SPECTRUM OF (ME3SI)3CLN(H)(MU-H)LI(THF)2(MU-H)IN(MU-H)(H)C(SIME3)3 (THF = TETRAHYDROFURAN)
AVENT, AG
EABORN, C
HITCHCOCK, PB
SMITH, JD
SULLIVAN, AC
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (13) : 988 - 989
[4] CHEMISTRY OF BORON .130. THE REACTION OF ORGANO-LITHIUM COMPOUNDS WITH BORANE DONORS - PREPARATION AND ISOLATION OF LITHIUM MONOORGANOTRIHYDROBORATES
BIFFAR, W
NOTH, H
SEDLAK, D
[J]. ORGANOMETALLICS, 1983, 2 (05) : 579 - 585
[5] PREPARATION OF TERTIARY PHOSPHINE COMPLEXES OF TETRAVALENT AND TRIVALENT URANIUM METHYLTRIHYDROBORATES - CRYSTAL-STRUCTURES OF TETRAKIS(METHYLTRIHYDROBORATO)(1,2-BIS(DIMETHYLPHOSPHINO)ETHANE)URANIUM(IV) AND TRIS(METHYLTRIHYDROBORATO)BIS(1,2-BIS(DIMETHYLPHOSPHINO)ETHANE)URANIUM(III)
BRENNAN, J
SHINOMOTO, R
ZALKIN, A
EDELSTEIN, N
[J]. INORGANIC CHEMISTRY, 1984, 23 (25) : 4143 - 4146
[6] INVESTIGATIONS IN THE SYNTHESIS OF ALKYL-SUBSTITUTED BOROHYDRIDES
BROWN, HC
SINGARAM, B
SINGARAM, S
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1982, 239 (01) : 43 - 64
[7] SOME STERICALLY HINDERED LITHIUM ALKYLBROMO-MAGNESATE AND ALKYLCHLORO-MAGNESATE, CADMATES, AND MANGANATES - CRYSTAL AND MOLECULAR-STRUCTURES OF [LI(THF)2(MU-BR)2MG(C(SIME3)3)(THF)], [LI(THF)4][(CD[C(SIME3)3])3(MU-BR)3(MU-3-BR)].0.5C6H12' [(LI(THF))3(MU-3-BR)3(MU-3-OSIME3)CD(C(SIME3)3)], AND [LI(THF)4][(MN[C(SIME3)3])3-(MU-CL)4(THF)] (THF = TETRAHYDROFURAN)H
BUTTRUS, NH
EABORN, C
ELKHELI, MNA
HITCHCOCK, PB
SMITH, JD
SULLIVAN, AC
TAVAKKOLI, K
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1988, (02): : 381 - 391
[8] ALANAT-SYNTHESE AUS DEN ELEMENTEN UND IHRE BEDEUTUNG
CLASEN, H
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1961, 73 (10) : 322 - &
[9] CRYSTAL-STRUCTURE OF THE TETRAHYDROFURAN ADDUCT OF TRIS(TRIMETHYLSILYL)-METHYL-LITHIUM, [LI(THF)4][LI(C(SIME3)3)2], AN ATE DERIVATIVE OF LITHIUM
EABORN, C
HITCHCOCK, PB
SMITH, JD
SULLIVAN, AC
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (15) : 827 - 828
[10] THE CRYSTAL-STRUCTURE OF THE ALKYLTRIHYDROBORATE [(THF)3LI(MU-H)3BC(SIME2PH)3], (THF = TETRAHYDROFURAN)
EABORN, C
ELKHELI, MNA
HITCHCOCK, PB
SMITH, JD
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (24) : 1673 - 1674

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