WATER-SOLUBLE PHOSPHANES .1. A NEW ROUTE TO WATER-SOLUBLE PHOSPHANES WITH PARA-SULFONATED PHENYL SUBSTITUENTS - CRYSTAL-STRUCTURE OF P(C6H4-P-SO3K)3.KCL.0.5H2O

被引：46

作者：

HERD, O

LANGHANS, KP

STELZER, O

WEFERLING, N

SHELDRICK, WS

机构：

[1] UNIV GESAMTHSCH WUPPERTAL, ANORGAN CHEM FACHBEREICH 9, GAUSSSTR 20, D-42097 WUPPERTAL, GERMANY

[2] HOECHST AG, WERK KNAPSACK, KNAPSACK, GERMANY

[3] RUHR UNIV BOCHUM, LEHRSTUHL ANALYT CHEM, W-4630 BOCHUM, GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1993年 / 32卷 / 07期

关键词：

D O I：

10.1002/anie.199310581

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the superbasic medium dimethylsulfoxide/KOH, potassium p-fluorobenzene-sulfonate (1) can be treated with PH3 [Eq. (a)], or primary or secondary phosphanes to afford water-soluble phosphanes (3) containing sulfonated aromatic groups. The trianion [P(C6H4-p-SO3-)3] in 2 . KCl . 0.5H2O is the first in this class of compounds that could be characterized by X-ray crystallography.

引用

页码：1058 / 1059

页数：2

共 15 条

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