SYNTHESIS AND CRYSTAL-STRUCTURE OF THE FIRST INVERSE 12-METALLACROWN-4

被引：84

作者：

STEMMLER, AJ ^{[1
]}

KAMPF, JW ^{[1
]}

PECORARO, VL ^{[1
]}

机构：

[1] UNIV MICHIGAN,DEPT CHEM,ANN ARBOR,MI 48109

来源：

INORGANIC CHEMISTRY | 1995年 / 34卷 / 09期

关键词：

D O I：

10.1021/ic00113a005

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex inv(OH)2[12-MC(Zn)2 + (N(pko))-4], 1, is the first example of a charged reversed analog of a 12-metallacrown-4. The structure poises charged zinc atoms toward a central cavity that contains two mu 3-bridging bridging OH- groups. This molecule illustrates how metallacrowns may be modified to serve primarily as anion recognition agents and is conceptually related to anticrowns such as 12-mercuracarborand-4.

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页码：2271 / 2272

页数：2

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