MOLECULAR RYDBERG STATES - AZULENE AND 4,6,8-TRIMETHYLAZULENE

被引：5

作者：

BOULER, D

FELPS, WS

LEWIS, J

NAUMAN, RV

MCGLYNN, SP

机构：

[1] Choppin Chemical Laboratories, The Louisiana State University, Baton Rouge

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 67卷 / 2-3期

基金：

美国能源部;

关键词：

D O I：

10.1016/0009-2614(79)85193-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The absorption spectra of azulene and 4,6,8-trimethylazulene are reported in the 1100-2200 A region. Two d-Rydberg series, both terminal on the first ionization potential I(I), are assigned. The lack of structure beyond the I(I) limit is attributed to autoionization events. The lowest-energy s- and p-Rydberg series members are expected to occur in the intravalence excitation region S4, S3, S2 - S0 and they may well be crucial to an interpretation of the spectroscopic peculiarities of this intravalence region. © 1979.

引用

页码：420 / 423

页数：4

共 8 条

[1] Ionization Potential of Azulene [J].