VIBRATIONAL AND ELECTRONIC EFFECTS OF NO CHEMISORPTION ON TIO2 AND RU/TIO2

被引：34

作者：

BOCCUZZI, F

GUGLIELMINOTTI, E

SPOTO, G

机构：

[1] Dipartimento di Chimica Inorganica, Chimica Fisica e Chimica dei Materiali, 10125 Torino

来源：

SURFACE SCIENCE | 1991年 / 251卷

关键词：

CO; ADSORPTION; REDUCTION; SURFACES; RU(001); OXYGEN; IR;

D O I：

10.1016/0039-6028(91)91152-N

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

NO adsorption on differently pretreated pure TiO2 and Ru/TiO2 samples has been investigated using FTIR spectroscopy. The analysis of the IR spectra concerns both the variations of the IR transparency, related to the electronic properties of the samples, and the vibrational modes of the adsorbed species. The experimental results are discussed taking into account the reducibility of the titania and the effect of the different valence states of Ru on the electronic and chemical behavior of this system.

引用

页码：1069 / 1074

页数：6

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