PHOTOTHERMAL SPECTROSCOPY WITH FEMTOJOULE SENSITIVITY USING A MICROMECHANICAL DEVICE

被引:266
作者
BARNES, JR [1 ]
STEPHENSON, RJ [1 ]
WELLAND, ME [1 ]
GERBER, C [1 ]
GIMZEWSKI, JK [1 ]
机构
[1] IBM CORP,DIV RES,ZURICH RES LAB,CH-8803 RUSCHLIKON,SWITZERLAND
关键词
D O I
10.1038/372079a0
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
WHEN a material absorbs a photon, a fraction of the energy may be transformed into heat. A measurement of photothermal heating as a function of wavelength can provide an absorption spectrum of the material. We have recently(1,2) developed a micromechanical sensor capable of detecting heat changes of the order of picojoules (10(-12) J). The instrument incorporates a bilayer cantilever of micrometre dimensions which bends in response to heating. Here we show that this device can be used for photothermal spectroscopy with a power sensitivity of 100 pW-two orders of magnitude better than the sensitivity of conventional photothermal deflection spectroscopy(3). The small size of the sensor allows picogram quantities of material to be studied, opening up the possibility of spectroscopic studies on individual cells and bacteria. Being based on silicon technology, the sensor should be compatible with microelectronic circuitry.
引用
收藏
页码:79 / 81
页数:3
相关论文
共 14 条
[1]   LASER THERMAL EFFECTS ON ATOMIC FORCE MICROSCOPE CANTILEVERS [J].
ALLEGRINI, M ;
ASCOLI, C ;
BASCHIERI, P ;
DINELLI, F ;
FREDIANI, C ;
LIO, A ;
MARIANI, T .
ULTRAMICROSCOPY, 1992, 42 :371-378
[2]  
AMER NM, 1984, SEMICONDUCT SEMIMET, V21, P83
[3]   PHOTOTHERMAL SPECTROSCOPY USING A PYROELECTRIC THIN-FILM DETECTOR [J].
COUFAL, H .
APPLIED PHYSICS LETTERS, 1984, 44 (01) :59-61
[4]  
Fournier D., 1987, Photoacoustic and thermal wave phenomena in semiconductors, P237
[5]   OBSERVATION OF A CHEMICAL-REACTION USING A MICROMECHANICAL SENSOR [J].
GIMZEWSKI, JK ;
GERBER, C ;
MEYER, E ;
SCHLITTLER, RR .
CHEMICAL PHYSICS LETTERS, 1994, 217 (5-6) :589-594
[6]   MOLECULAR MIMICRY OF PHOTOSYNTHETIC ENERGY AND ELECTRON-TRANSFER [J].
GUST, D ;
MOORE, TA ;
MOORE, AL .
ACCOUNTS OF CHEMICAL RESEARCH, 1993, 26 (04) :198-205
[7]  
James A.M., 1987, THERMAL ENERGETIC ST
[8]   MECHANICAL AND THERMAL EFFECTS OF LASER IRRADIATION ON FORCE MICROSCOPE CANTILEVERS [J].
MARTI, O ;
RUF, A ;
HIPP, M ;
BIELEFELDT, H ;
COLCHERO, J ;
MLYNEK, J .
ULTRAMICROSCOPY, 1992, 42 :345-350
[9]  
MEYER E, IN PRESS ULTIMATE LI
[10]   NOVEL OPTICAL APPROACH TO ATOMIC FORCE MICROSCOPY [J].
MEYER, G ;
AMER, NM .
APPLIED PHYSICS LETTERS, 1988, 53 (12) :1045-1047