A BRANCHED-MONOMER APPROACH FOR THE RAPID SYNTHESIS OF DENDIMERS

被引:121
作者
WOOLEY, KL [1 ]
HAWKER, CJ [1 ]
FRECHET, JMJ [1 ]
机构
[1] CORNELL UNIV,DEPT CHEM,BAKER LAB,ITHACA,NY 14853
来源
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 01期
关键词
D O I
10.1002/anie.199400821
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An accelerated route to the synthesis of dendritic macromolecules through the use of fractal components larger than the repeating unit is described. The first‐generation bromide 1 and the second‐generation novel branched AB4 monomer 2 can be used to prepare a highly regular fifth‐generation poly(ether ester) dendrimer (Mr = 9371) in only three synthetic steps. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany
引用
收藏
页码:82 / 85
页数:4
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