STEREOCHEMISTRY OF ORGANOMERCURY COMPOUNDS .2. A REDETERMINATION OF STRUCTURE OF MERCURY(2) CYANIDE BY NEUTRON DIFFRACTION

被引：57

作者：

SECCOMBE, RC

KENNARD, CHL

机构：

[1] Department of Chemistry, University of Queensland, Brisbane

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1969年 / 18卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)85392-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure of mercury(II) cyanide, Hg(CN)2, has been determined using three dimensional neutron diffraction data. The compound crystallizes out in a tetragonal unit cell, space group I42d; cell dimensions, a = 9.643, c = 8.88 ». There are eight molecules per unit cell. Interatomic distances and angles are: Hg-C, 2.015(3); C-N, 1.137(3); non bonding Hg-N, 2.742(3) »; C-Hg-C, 175.0(2)°; Hg-C-N, 177.0(3)°. © 1969.

引用

页码：243 / &

共 8 条

[1] ELCOMBE M, PRIVATE COMMUNICATIO
[2] A COMBINED X-RAY AND NEUTRON DIFFRACTION INVESTIGATION OF MERCURIC CYANIDE
HVOSLEF, J
[J]. ACTA CHEMICA SCANDINAVICA, 1958, 12 (08): : 1568 - 1574
[3] CRYSTAL STRUCTURE OF KI.HG(CN2)
KRUSE, FH
[J]. ACTA CRYSTALLOGRAPHICA, 1963, 16 (02): : 105 - &
[4] KUNCHUR NR, 1964, P CHEM SOC LONDON, P414
[5] CRYSTAL STRUCTURE OF BISPENTAFLUOROPHENYLMERCURY
KUNCHUR, NR
MATHEW, M
[J]. CHEMICAL COMMUNICATIONS, 1966, (03) : 71 - &
[6] CRYSTAL STRUCTURE OF METHYLMERCURY(2) CYANIDE
MILLS, JC
PRESTON, HS
KENNARD, CHL
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1968, 14 (01) : 33 - &
[7] ZIOLKOWSKA B, 1962, ROCZ CHEM, V36, P1341
[8] Ziolkowska B., 1964, J STRUCT CHEM, V5, P678

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