STABLE ACYLS AND IMINOACYLS OF ZIRCONIUM(IV), [ZR(ETA-C5H5)2[C(-X)R]R'] [X = O OR NTO1-P-R = ME3CCH2, ME3SICH2, OR (ME3SI)2 CH-R' = CL OR ALKYL]

被引：75

作者：

LAPPERT, MF

LUONGTHI, NT

MILNE, CRC

机构：

[1] School of Molecular Sciences, University of Sussex, Brighton

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 174卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)91511-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Insertion of CO or p-TolNC into a ZrC bond of [Zr(η-C5H5).(R)R′] under ambient conditions in C6H6 leads to the stable η2-acyl- or η2-iminoacyl-complex [Zr(η-C5H5)2{η2-C(X)R}R′] (X = O or NTol-p); with [Zr(η-C5H5)2{CH(SiMe3)2}Me] as substrate there is exclusive preference for scission of the more hindered ZrC bond. © 1979.

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页码：C35 / C37

页数：3

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