SYNTHESIS OF SIGMA-ALKYL DIKETONATO AND MONOTHIO BETA-DIKETONATO COMPLEXES OF PLATINUM(II) AND PALLADIUM(II)

被引：13

作者：

JIN, H ^{[1
]}

CAVELL, KJ ^{[1
]}

机构：

[1] UNIV TASMANIA,DEPT CHEM,HOBART,TAS 7001,AUSTRALIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 419卷 / 1-2期

基金：

澳大利亚研究理事会;

关键词：

D O I：

10.1016/0022-328X(91)86181-O

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A variety of Pt(II) and Pd(II) sigma-methyl complexes of general formula MMe(beta-dik)(PPh3) (M = Pt, Pd; beta-dik = beta-diketonate or monothio-beta-diketonate ligands) have been prepared and fully characterized. The structures of the complexes are very sensitive to the nature of the beta-dik ligand, both in terms of the coordinating atoms (O,O or O,S) and with respect to the moieties attached to the backbone of the beta-dik ligand. In complexes containing the monothio-beta-diketonate ligand the sigma-methyl ligand always selects a coordination site that is predominantly trans to the oxygen atom.

引用

页码：259 / 268

页数：10

共 30 条

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