POLYENOLATES OF UNSATURATED CARBOXYLIC-ACIDS IN SYNTHESIS - SYNTHESIS OF UNSATURATED ALPHA-AMINO-ACIDS AND GAMMA-HYDRAZINO ACIDS

被引：7

作者：

AURELL, MJ ^{[1
]}

GIL, S ^{[1
]}

MARTINEZ, PV ^{[1
]}

PARRA, M ^{[1
]}

TORTAJADA, A ^{[1
]}

MESTRES, R ^{[1
]}

机构：

[1] UNIV VALENCIA,FAC QUIM,DEPT QUIM ORGAN,VALENCIA,SPAIN

来源：

SYNTHETIC COMMUNICATIONS | 1991年 / 21卷 / 18-19期

关键词：

D O I：

10.1080/00397919108021773

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Regioselective reaction of lithium dieneand triene-diolates 1 and 2 with o-diphenylphosphinyl hydroxylamine affords unsaturated alpha-amino acids 3 and 4. Addition to DEAD leads selectively to gamma-hydrazino unsaturated acids 5 and 6.

引用

页码：1833 / 1839

页数：7

共 15 条

[1] AURELL MJ, 1990, SYNTHESIS-STUTTGART, P317
[2] BALDWIN JE, 1989, TETRAHEDRON, V45, P6330
[3] UNSATURATED CARBOXYLIC-ACID POLYENOLATES - LITHIUM TRIENOLATE OF SORBIC ACID AS A D6 SYNTHON - ADDITION TO KETONES AND UNSATURATED-KETONES
BALLESTER, P
COSTA, A
GARCIARASO, A
MESTRES, R
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1988, (10): : 2797 - 2803
[4] BOCHE G, 1982, TETRAHEDRON LETT, V23, P5399
[5] SYNTHESIS OF UNSATURATED 5-HYDROXY-ACIDS AND 7-OXO-ACIDS BY ADDITION OF UNSATURATED CARBOXYLIC-ACID DIENOLATES TO CARBONYL-COMPOUNDS
CASINOS, I
MESTRES, R
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1978, (12): : 1651 - 1655
[6] COLVIN EW, 1982, TETRAHEDRON LETT, V23, P3835, DOI 10.1016/S0040-4039(00)87720-5
[7] ELECTROPHILIC AMINATION OF CARBANIONS
ERDIK, E
AY, M
[J]. CHEMICAL REVIEWS, 1989, 89 (08) : 1947 - 1980
[8] HAGER MJP, 1981, J CHEM SOC P1, P3284
[9] UNUSUAL ALPHA-AMINOACIDS FROM VINYLGLYCINE
MEFFRE, P
VOQUANG, L
VOQUANG, Y
LEGOFFIC, F
[J]. TETRAHEDRON LETTERS, 1990, 31 (16) : 2291 - 2294
[10] SUICIDE SUBSTRATES - MECHANISM-BASED ENZYME INACTIVATORS
WALSH, C
[J]. TETRAHEDRON, 1982, 38 (07) : 871 - 909

← 1 2 →