LOW-TEMPERATURE SYNTHESES OF SODIUM AND COPPER VANADIUM OXIBRONZES

被引：3

作者：

BALLIVETTKATCHENKO, D ^{[1
]}

DELAHAY, G ^{[1
]}

GALY, J ^{[1
]}

PARIZE, JL ^{[1
]}

SAVARIAULT, JM ^{[1
]}

机构：

[1] CNRS,CTR ELABORAT MAT & ETUDES STRUCT,UNITE PROPRE 8011,F-31055 TOULOUSE,FRANCE

来源：

MATERIALS RESEARCH BULLETIN | 1991年 / 26卷 / 11期

关键词：

D O I：

10.1016/0025-5408(91)90124-5

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Low temperature preparations of vanadium oxibronzes were carried out to obtain finely divided powders in view of catalytic applications. From a commercial precursor V2O5, the reduction by LiI in acetonitrile led to delta-LiV2O5. The synthesis of alpha'-NaV2O5 was achieved for the first time at 373 K by the ionic exchange Li+/Na+ in aqueous solution. A new copper bronze, Cu0.5V2O5(H2O)0.5, was also prepared according to the same experimental procedure by Li+/Cu2+ or Na+/Cu2+ exchange. These lithium, sodium and copper bronzes exhibit surface areas ranging from 5 to 50 m2 g-1 which make them good candidates for catalytic studies.

引用

页码：1181 / 1184

页数：4

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