SILVER INSERTION MODE IN BETA-AGXV2O5 TUNNEL STRUCTURE

被引：35

作者：

DERAMOND, E

SAVARIAULT, JM

GALY, J

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1994年 / 50卷

关键词：

D O I：

10.1107/S0108270193007802

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The beta-AgxV2O5 phase of silver vanadate has a large homogeneity range, 0.29 less-than-or-equal-to x less-than-or-equal-to 0.41; the (V2O5), network of its crystal structure is typical of the beta phase of the vanadium oxide bronzes with its oxygenated tunnels running along [010]. Ag atoms are inserted in a novel manner, being distributed onto two distinct crystallographic sites, which explains the overstepping of the theoretical boundary limit of the beta phases, x = 0.33.

引用

页码：164 / 166

页数：3

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