ELECTRON RESONANCE SPECTRUM OF GASEOUS SE0 IN ITS 3SIGMA AND 1DELTA STATES

被引：29

作者：

CARRINGTON, A

CURRIE, GN

LEVY, DH

MILLER, TA

机构：

[1] Department of Chemistry, University of Southampton, Hampshire

[2] James Franck Institute, University of Chicago, IL

[3] Bell Telephone Laboratories, Murray Hill, NJ

来源：

MOLECULAR PHYSICS | 1969年 / 17卷 / 05期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1080/00268976900101381

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The gas phase electron resonance spectrum of SeO in its 3Σ and 1Δ states has been studied. Values of the rotational constant B0 and ‘spin-spin’ splitting parameter λ in the 3Σ state, previously determined from the ultraviolet spectrum, are shown to be consistent with the electron resonance results, and we are also able to estimate the spin-rotation interaction constant. In addition, the 3Σ spectrum shows 77Se hyperfine structure. The 1Δ spectrum yields values for the rotational constant (and hence bond length) and rotational g factor. © 1969 Taylor and Francis Group, LLC.

引用

页码：535 / +

页数：1

共 18 条

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