SYNTHESIS AND CHARACTERIZATION OF THE LINEAR TRINUCLEAR COMPLEXES [MN-3(2)(O2CCH3)6(BIPHME)2, [FE-3(2)(O2CCH3)6(BIPHME)2]

被引：97

作者：

RARDIN, RL ^{[1
]}

BINO, A ^{[1
]}

POGANIUCH, P ^{[1
]}

TOLMAN, WB ^{[1
]}

LIU, SC ^{[1
]}

LIPPARD, SJ ^{[1
]}

机构：

[1] MIT, DEPT CHEM, CAMBRIDGE, MA 02139 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1990年 / 29卷 / 07期

关键词：

D O I：

10.1002/anie.199008121

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A Mn3 chain bridged by four bidentate and two monodentate carboxylate ligands characterizes the MnII title complex 1. Unique features are the monodentate acetate bridges, which have a “dangling” oxygen atom that influences the molecular structure through weak interactions with the terminal Mn atoms. (Figure Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

引用

收藏

页码：812 / 814

页数：3

相关论文

共 51 条

[1]

Alcala R., 1973, Revista de la Academia de Ciencias Zaragoza, V28, P303

[2] SYNTHESIS, STRUCTURE, AND MAGNETIC-PROPERTIES OF THE STABLE TRIANGULAR [MNIV3O4]4+ CORE [J].

AUGER, N ;

GIRERD, JJ ;

CORBELLA, M ;

GLEIZES, A ;

ZIMMERMANN, JL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (01) :448-450

[3] A GENERAL-METHOD FOR ASSEMBLING (MU-OXO)BIS(MU-CARBOXYLATO)DIIRON(III) COMPLEXES WITH LABILE TERMINAL SITES USING A BRIDGING DICARBOXYLATE LIGAND [J].

BEER, RH ;

TOLMAN, WB ;

BOTT, SG ;

LIPPARD, SJ .

INORGANIC CHEMISTRY, 1989, 28 (26) :4557-4559

[4] CRYSTAL-STRUCTURE OF MANGANESE ACETATE TETRAHYDRATE [J].

BERTAUT, EF ;

DUC, TQ ;

BURLET, P ;

THOMAS, M ;

MOREAU, JM .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1974, 30 (SEP15) :2234-2236

[5] A NEW MODEL FOR THE OXYGEN-EVOLVING COMPLEX IN PHOTOSYNTHESIS - A TRINUCLEAR MU-3-OXO-MANGANESE(222) COMPLEX WHICH CONTAINS A MU-PEROXO GROUP [J].

BHULA, R ;

GAINSFORD, GJ ;

WEATHERBURN, DC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (22) :7550-7552

[6]

BRUDVIG GW, 1988, ACS SYM SER, V372, P221

[7]

BRUDVIG GW, 1989, ANNU REV BIOPHYS BIO, V37, P99

[8] EVIDENCE THAT PROTEIN-B OF THE THIOSULFATE-OXIDIZING SYSTEM OF THIOBACILLUS-VERSUTUS CONTAINS A BINUCLEAR MANGANESE CLUSTER [J].

CAMMACK, R ;

CHAPMAN, A ;

LU, WP ;

KARAGOUNI, A ;

KELLY, DP .

FEBS LETTERS, 1989, 253 (1-2) :239-243

[9] SYNTHESIS, STRUCTURE AND MAGNETIC-PROPERTIES OF A DINUCLEAR MANGANESE(II) COMPLEX WITH ONE MU-AQUA AND 2 MU-CARBOXYLATO BRIDGES [J].

CANESCHI, A ;

FERRARO, F ;

GATTESCHI, D ;

MELANDRI, MC ;

REY, P ;

SESSOLI, R .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (10) :1365-1367

[10]

Caneschi A., 1989, ANGEW CHEM, V101, P1408

← 1 2 3 4 5 6 →