IONIC RECOGNITION BY PROTON-IONIZABLE LARIAT ETHERS AND THEIR POLYMERS

被引：31

作者：

BARTSCH, RA ^{[1
]}

KIM, JS ^{[1
]}

OLSHER, U ^{[1
]}

PURKISS, DW ^{[1
]}

RAMESH, V ^{[1
]}

DALLEY, NK ^{[1
]}

HAYASHITA, T ^{[1
]}

机构：

[1] BRIGHAM YOUNG UNIV,DEPT CHEM,PROVO,UT 84602

来源：

PURE AND APPLIED CHEMISTRY | 1993年 / 65卷 / 03期

关键词：

D O I：

10.1351/pac199365030399

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

To probe the influence of structural variation within dibenzo-16-crown-5-oxyacetic acids upon the selectivity of alkali metal cation separations by solvent extraction and liquid membrane transport processes, studies have now been conducted in homogeneous solution by NMR spectroscopy and titration calorimetry and in the solid state. Condensation polymerization of such proton-ionizable lariat ethers with formaldehyde produces a new class of ion-exchange resins which contain cyclic polyether binding sites as well as ion-exchange site for metal ion complexation.

引用

页码：399 / 402

页数：4

共 11 条

[1] SYNTHESIS AND ACIDITY OF CROWN ETHERS WITH PENDANT CARBOXYLIC-ACID GROUPS
BARTSCH, RA
HEO, GS
KANG, SI
LIU, Y
STRZELBICKI, J
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1982, 47 (03) : 457 - 460
[2] SYNTHESIS OF HIGHLY LIPOPHILIC CROWN ETHER CARBOXYLIC-ACIDS
BARTSCH, RA
LIU, Y
KANG, SI
SON, B
HEO, GS
HIPES, PG
BILLS, LJ
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1983, 48 (25) : 4864 - 4869
[3] EFFECTS OF STRUCTURAL VARIATION WITHIN PROTON-IONIZABLE CROWN ETHERS UPON THE SELECTIVITY AND EFFICIENCY OF SOLVENT-EXTRACTION OF ALKALI-METAL AND ALKALINE-EARTH CATIONS
BARTSCH, RA
[J]. SOLVENT EXTRACTION AND ION EXCHANGE, 1989, 7 (05) : 829 - 854
[4] COMPARISON OF HIGHLY LIPOPHILIC CROWN ETHER CARBOXYLIC-ACIDS FOR TRANSPORT OF ALKALI-METAL CATIONS FROM AQUEOUS-SOLUTIONS INTO CHLOROFORM
CHAREWICZ, WA
HEO, GS
BARTSCH, RA
[J]. ANALYTICAL CHEMISTRY, 1982, 54 (12) : 2094 - 2097
[5] PREORGANIZATION - FROM SOLVENTS TO SPHERANDS
CRAM, DJ
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1986, 25 (12): : 1039 - 1057
[6] LARIAT ETHERS - SYNTHESIS AND CATION BINDING OF MACROCYCLIC POLYETHERS POSSESSING AXIALLY DISPOSED SECONDARY DONOR GROUPS
GOKEL, GW
DISHONG, DM
DIAMOND, CJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1980, (22) : 1053 - 1054
[7] SELECTIVE SORPTION OF ALKALI-METAL CATIONS BY CARBOXYLIC-ACID RESINS CONTAINING ACYCLIC OR CYCLIC POLYETHER UNITS
HAYASHITA, T
GOO, MJ
LEE, JC
KIM, JS
KRZYKAWSKI, J
BARTSCH, RA
[J]. ANALYTICAL CHEMISTRY, 1990, 62 (21) : 2283 - 2287
[8] PREPARATION OF HYDROXY CROWN ETHERS BY REACTIONS OF DIPHENOLS WITH EPICHLOROHYDRIN
HEO, GS
BARTSCH, RA
SCHLOBOHM, LL
LEE, JG
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (17) : 3574 - 3575
[9] SOLVENT-EXTRACTION OF ALKALI-METAL CATIONS FROM AQUEOUS-SOLUTIONS BY HIGHLY LIPOPHILIC CROWN ETHER CARBOXYLIC-ACIDS
STRZELBICKI, J
BARTSCH, RA
[J]. ANALYTICAL CHEMISTRY, 1981, 53 (14) : 2251 - 2253
[10] EXTRACTION OF ALKALI-METAL CATIONS FROM AQUEOUS-SOLUTIONS BY A CROWN ETHER CARBOXYLIC-ACID
STRZELBICKI, J
BARTSCH, RA
[J]. ANALYTICAL CHEMISTRY, 1981, 53 (12) : 1894 - 1899

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