REACTION PATHWAYS FOR THE OLIGOMERIZATION OF ORGANIC ISOCYANIDES BY TANTALUM HYDRIDE REAGENTS

被引：26

作者：

CLARK, JR ^{[1
]}

FANWICK, PE ^{[1
]}

ROTHWELL, IP ^{[1
]}

机构：

[1] PURDUE UNIV,DEPT CHEM,1393 BROWN BLDG,W LAFAYETTE,IN 47907

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 15期

关键词：

D O I：

10.1039/c39930001233

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The tantalum monohydride compound [Ta(OAr)2Cl2(H)(PMe2Ph)2] (OAr = 2,6-diisopropylphenoxide) will react with one, two or three equivalents or organic isocyanides to produce a sequence of organometallic products resulting from initial insertion into the Ta-H bond and subsequent coupling reactions.

引用

页码：1233 / 1235

页数：3

共 7 条

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