LIGAND FIELD SPECTRA OF TRINUCLEAR CHROMIUM(3) AND IRON(3) BASIC ACETATES

被引：29

作者：

DUBICKI, L

MARTIN, RL

机构：

[1] Department of Inorganic Chemistry, University of Melbourne, Parkville, VIC

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1969年 / 22卷 / 04期

关键词：

D O I：

10.1071/CH9690701

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The visible spectra of trinuclear chromium(III) acetates [Cr3O(CH3CO2)6R2]+ can be successfully analysed by means of the ligand field theory for tetragonal fields. The ligands R (R = H2O, NH3, py, DMSO) are relatively labile and may be replaced by several ligands of varying donor strength. The spectra of trinuclear iron(III) acetates [Fe3O(CH3CO2)6R3]+ are poorly resolved but can be interpreted on the basis of a d5 configuration in octahedral fields. © 1969, CSIRO. All rights reserved.

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页码：701 / &

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