Triplet states of acetylene by electron impact

被引：47

作者：

Trajmar, S. ^{[1
]}

Rice, J. K. ^{[1
]}

Wei, P. S. P. ^{[1
]}

Kuppermann, A. ^{[1
]}

机构：

[1] CALTECH, Gate & Crellin Labs Chem, Pasadena, CA 91109 USA

来源：

CHEMICAL PHYSICS LETTERS | 1968年 / 1卷 / 13期

关键词：

D O I：

10.1016/0009-2614(68)80126-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Low-energy electron-impact spectroscopy has revealed two previously unknown low-lying triplet states in acetylene at 5.2 eV and 6.1 eV. The basis for this identification and the disparity in the electron energy-loss and optical absorption spectra are discussed.

引用

页码：703 / 705

页数：3

共 16 条

[1] VALENCE-BOND CALCULATIONS OF TRIPLET-STATE ENERGIES AND SPIN DENSITIES OF UNSATURATED ORGANIC MOLECULES
BARFIELD, M
[J]. JOURNAL OF CHEMICAL PHYSICS, 1967, 47 (10) : 3831 - &
[2] EXCITATION OF METHANE ETHANE ETHYLENE PROPYLENE ACETYLENE PROPYNE AND 1-BUTYNE BY LOW-ENERGY ELECTRON BEAMS
BOWMAN, CR
MILLER, WD
[J]. JOURNAL OF CHEMICAL PHYSICS, 1965, 42 (02) : 681 - &
[3] SP-O (SPLIT-P-ORBITAL) METHOD .2. FURTHER DEFINITION AND APPLICATION TO ACETYLENE
DEWAR, MJ
HOJVAT, NL
[J]. PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1961, 264 (1318) : 431 - +
[4] DOUGLAS AE, UNPUB, P517
[5] Herzberg G., 1966, MOL SPECTRA MOL STRU
[6] ANOMALOUS ROTATIONAL LINE INTENSITIES IN ELECTRONIC TRANSITIONS OF POLYATOMIC MOLECULES - AXIS-SWITCHING
HOUGEN, JT
WATSON, JKG
[J]. CANADIAN JOURNAL OF PHYSICS, 1965, 43 (02) : 298 - &
[7] EXCITED STATES OF ACETYLENE .1. POSSIBILITIES OF INTERACTION BETWEEN SIGMA-BOND HYBRIDISATION AND PI-ELECTRON EXCITATION WITH RESULTING CHANGES OF SHAPE DURING TRANSITIONS
INGOLD, CK
KING, GW
[J]. JOURNAL OF THE CHEMICAL SOCIETY, 1953, (SEP): : 2702 - 2704
[8] THE BENT EXCITED STATE OF ACETYLENE
KING, GW
INGOLD, CK
[J]. NATURE, 1952, 169 (4313) : 1101 - 1102
[9] RICE JE, IN PRESS J CHEM PHYS
[10] CALCULATIONS OF THE ENERGY LEVELS OF ACETYLENE BY THE METHOD OF ANTISYMMETRIC MOLECULAR ORBITALS, INCLUDING SIGMA-PI-INTERACTION
ROSS, IG
[J]. TRANSACTIONS OF THE FARADAY SOCIETY, 1952, 48 (11): : 973 - 991

← 1 2 →