DELIVERY-CONTROL IN ORGANIC-REACTIVITY

被引：23

作者：

SHERROD, MJ ^{[1
]}

MENGER, FM ^{[1
]}

机构：

[1] EMORY UNIV,DEPT CHEM,ATLANTA,GA 30322

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 04期

关键词：

D O I：

10.1016/0040-4039(90)87007-M

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A large portion of the energy requirements of an intramolecular hydride transfer was shown to entail a carbon skeleton distortion that delivers the hydrogen to the recipient carbon. Only after a critical distance is reached does actual chemical reaction begin. © 1990.

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页码：459 / 462

页数：4

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