A Vibrational-Spectroscopic Study of the Species Present in the CO(2)-H(2)O System

被引：165

作者：

Davis, A. R. ^{[1
]}

Oliver, B. G. ^{[1
]}

机构：

[1] Dept Environm, Inland Waters Branch, Ottawa, ON, Canada

来源：

JOURNAL OF SOLUTION CHEMISTRY | 1972年 / 1卷 / 04期

关键词：

Raman; infrared; carbon dioxide; bicarbonate; carbonate; water; deuterium oxide; structure;

D O I：

10.1007/BF00715991

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Raman and infrared spectra have been recorded of water and heavy-water solutions of carbon dioxide, potassium bicarbonate, and potassium carbonate. The structures of the carbonate and bicarbonate ions and CO(2) (aqueous solution) have been determined from a consideration of Raman and infrared data. The results reveal the presence of solvent effects in the carbonate and CO(2) water solutions. No bands characteristic of H(2)CO(3) were observed in the Raman spectrum of aqueous solutions of CO(2).

引用

页码：329 / 339

页数：11

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