SYNTHESIS OF ALKYL HYDROPEROXIDES BY HYDROPEROXYMERCURIATION AND REDUCTION

被引：9

作者：

BLOODWORTH, AJ

COOKSEY, CJ

KORKODILOS, D

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 13期

关键词：

D O I：

10.1039/c39920000926

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Alkyl hydroperoxides, R1R2C(OOH)CH2R3, have been prepared from 30% hydrogen peroxide by hydroperoxymercuriation of the corresponding alkenes, R1R2C = CHR3, followed by addition to 2-methoxypropene, reductive demercuriation with basic sodium borohydride and deprotection of the resultant 2-methoxyprop-2-yl derivatives, R1R2C(OOCMe2OMe)CH2R3, with aqueous acetic acid.

引用

页码：926 / 927

页数：2

共 5 条

[1] OXYMETALATION .16. MODIFIED PROCEDURES FOR REDUCING PEROXYMERCURIALS - CONVERSION OF NON-TERMINAL ALKENES INTO SECONDARY ALKYL TERT-BUTYL PEROXIDES [J].