ELECTRON-IMPACT FRAGMENTATION OF POLYCHLORINATED BRIDGED-RING SYSTEMS

被引：7

作者：

BINKS, R

MACKENZI.K

WILLIAMS.DL

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 11期

关键词：

D O I：

10.1039/j39690001528

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Mass spectrographic analysis of a number of polychlorinated bridged-ring compounds based on the norbornene skeleton is described. The compounds examined have been grouped into classes according to their behaviour. Retro-Diels - Alder reactions (RDA), bond switching followed by 1,2-elimination, bridge scission with concomitant chlorine loss, stepwise chlorine elimination, and sigmatropic hydrogen transfer are processes which could be envisaged to account for the fragmentations observed.

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页码：1528 / &

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