A NOVEL SYNTHESIS OF 1,3,5-TRIAZINE DERIVATIVE UNDER HIGH-PRESSURE

被引：4

作者：

TAGUCHI, Y

YASUMOTO, M

TSUCHIYA, T

OISHI, A

SHIBUYA, I

机构：

来源：

CHEMISTRY LETTERS | 1993年 / 07期

关键词：

D O I：

10.1246/cl.1993.1097

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

5,6-Dihydro-1,3,5-trimethyl-6-methylimino- 1,3,5-triazine-2,4-(1H,3H)-dithione (1) was synthesized by the reaction of methyl isothiocyanate under high pressure in the presence of Et3N and H2O. The yield and selectivity of 1 were seriously effected by pressure, reaction temperature, solvent, and the amount of H2O.

引用

页码：1097 / 1100

页数：4

共 7 条

[1]

JOSHUA CP, 1982, SYNTHESIS-STUTTGART, P1070

[2] REACTION OF NITRILES UNDER HIGH-PRESSURE .1. FORMATION OF TRIPHENYL-1,3,5-TRIAZINE VIA EQUILIBRIUM AMONG BENZONITRILE, ALCOHOLS, AND BENZIMINOETHERS [J].