REACTIONS OF EPOXIDES .20. PREPARATION AND SOME REACTIONS OF EPOXIDES OF 3- 6- AND 7-METHYLENECHOLESTANE DERIVATIVES

被引：34

作者：

BLACKETT, BN

COXON, JM

HARTSHOR.MP

JACKSON, BLJ

MUIR, CN

机构：

[1] Department of Chemistry, University of Canterbury, Christchurch

来源：

TETRAHEDRON | 1969年 / 25卷 / 07期

关键词：

D O I：

10.1016/S0040-4020(01)82719-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The BF3-catalysed rearrangements of exocyclic methylene epoxides at C-3, C-6, C-7 and C-12 give mixtures of epimeric aldehydes. These results are explained on the basis of the involvement of discrete carbonium ion intermediates in the rearrangement processes. © 1969.

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页码：1479 / &

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