EFFECT OF PRESSURE AND TEMPERATURE ON CONDUCTIVITY AND IONIC DISSOCIATION OF WATER UP TO 100 KBAR AND 1000 DEGREES C

被引：102

作者：

HOLZAPFEL, WB

机构：

[1] Institut für Physikalische Chemie, Universität Karlsruhe, Karlsruhe

来源：

JOURNAL OF CHEMICAL PHYSICS | 1969年 / 50卷 / 10期

关键词：

D O I：

10.1063/1.1670914

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The effect of pressure and temperature on the equivalent conductance of water is derived from recent conductivity measurements. The results together with experimental data on the ionic conductivity of water at temperatures up to 1000°C and pressures up to 100 kbar are discussed. The ionic product of water and the corresponding thermodynamic data for water dissociation at high pressures and temperatures are derived.

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页码：4424 / +

页数：1

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共 34 条

[1] APPARENT MOLAR VOLUME OF SODIUM HYDROXIDE AT INFINITE DILUTION AND VOLUME CHANGE ACCOMPANYING IONIZATION OF WATER [J].

BODANSZKY, A ;

KAUZMANN, W .

JOURNAL OF PHYSICAL CHEMISTRY, 1962, 66 (01) :177-&

[2]

BRADLEY RS, 1963, HIGH PRESSURE PHY ED, V1, P215

[3] Water, in the liquid and five solid forms, under pressure [J].

Bridgman, PW .

PROCEEDINGS OF THE AMERICAN ACADEMY OF ARTS AND SCIENCES, 1912, 47 (13/22) :441-558

[4] Pressure-volume relations for seventeen elements to 100,000 kg/cm [J].

Bridgman, PW .

PROCEEDINGS OF THE AMERICAN ACADEMY OF ARTS AND SCIENCES, 1942, 74 (12/14) :425-440

[5] The phase diagram of water to 45,000 kg/cm(2) [J].

Bridgman, PW .

JOURNAL OF CHEMICAL PHYSICS, 1937, 5 (12) :964-966

[6]

BRISH AA, 1960, SOV PHYS JETP-USSR, V11, P15

[7]

COBBLE JW, 1964, J AM CHEM SOC, V86, P5399

[8] IONIZATION CONSTANT OF DEUTERIUM OXIDE FROM 5 TO 50 DEGREES [J].

COVINGTON, AK ;

ROBINSON, RA ;

BATES, RG .

JOURNAL OF PHYSICAL CHEMISTRY, 1966, 70 (12) :3820-+

[9] THE CHEMICAL EFFECTS OF PRESSURE .6. THE ELECTRICAL CONDUCTIVITY OF SEVERAL LIQUIDS AT HIGH SHOCK PRESSURES [J].

DAVID, HG ;

HAMANN, SD .

TRANSACTIONS OF THE FARADAY SOCIETY, 1960, 56 (07) :1043-1050

[10] THE CHEMICAL EFFECTS OF PRESSURE .5. THE ELECTRICAL CONDUCTIVITY OF WATER AT HIGH SHOCK PRESSURES [J].

DAVID, HG ;

HAMANN, SD .

TRANSACTIONS OF THE FARADAY SOCIETY, 1959, 55 (01) :72-78

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