DOUBLE HALIDE ION AFFINITIES OF METAL TETRAHALIDES AND ASSOCIATED BOND STRENGTHS

被引：12

作者：

JENKINS, HDB ^{[1
]}

PRATT, KF ^{[1
]}

机构：

[1] UNIV WARWICK,SCH CHEM & MOLEC SCI,COVENTRY CV4 7AL,WARWICKSHIRE,ENGLAND

来源：

INORGANICA CHIMICA ACTA | 1979年 / 32卷 / 01期

关键词：

D O I：

10.1016/S0020-1693(00)91633-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Double halide ion affinities corresponding to the process: {A figure is presented} are calculated (M = Ti. Si, Ge, X = F; M = Ti, Zr, Hf, Nb, Ta, Mo, W, Os, Ge, Sn, Pb and Te, X = Ti; M = Ti, X = Br) from lattice energy studies and acceptor power towards Cl- is as follows: {A figure is presented} Homo and heterolytic bond structures are then calculated and the transition metal-chlorine bond strengths show the following periodic trends: {A figure is presented} The actinide metal-clorine bond strengths are in the order: {A figure is presented}. © 1979.

引用

页码：25 / 28

页数：4

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