EQUILIBRIA IN PROPYLENE CARBONATE .I. VISCOSITY AND CONDUCTANCE STUDIES OF SOME LITHIUM AND QUATERNARY AMMONIUM SALTS

被引：89

作者：

MUKHERJEE, LM

BODEN, DP

机构：

[1] Chemistry Department, Polytechnic Institute of Brooklyn, Brooklyn

[2] Chemistry Department, Illinois State University, Normal

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1969年 / 73卷 / 11期

关键词：

D O I：

10.1021/j100845a068

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Results of conductance and viscosity measurements of solutions of LiCl, LiBr, LiClO4, Et4NCl, Et4NClO4 n-Bu4NBr, and n-Bu4NClO4 in propylene carbonate are reported. All conductance data have been treated by the method of Fuoss and Accascina. Lithium chloride and lithium bromide are found to be associated, having association constants of 557 and 19, respectively, whereas no association could be detected for the other systems. The significance of the values of viscosity F coefficient and a0 parameter in different cases is discussed.

引用

页码：3965 / +

页数：1

共 18 条

[1] CAN IONIC CONCENTRATIONS IN DIETHYL ETHER BE DETERMINED BY EMF MEASUREMENTS [J].