STEREOSELECTIVE SYNTHESIS OF 4A-METHYLOCTAHYDROPHENANTHRENES - NOVEL-APPROACH .1. C-2 AND C-3 SUBSTITUTED SERIES

被引：15

作者：

CAMPBELL, AL ^{[1
]}

LEADER, HN ^{[1
]}

SPENCER, CL ^{[1
]}

MCCHESNEY, JD ^{[1
]}

机构：

[1] UNIV KANSAS,SCH PHARM,DEPT MED CHEM,LAWRENCE,KS 66045

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 15期

关键词：

D O I：

10.1021/jo01329a031

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The regio-and stereoselective syntheses of variously C-2 and C-3 functionalized 4a-methyloctahydrophenanthrenes are described. The diene, 4a-methyl-Δ1(10a),3(4)-tetrahydrophenanthrene, is a key synthon and is readily prepared from phenanthrene. The chemical verification of stereochemistry is accomplished. © 1979, American Chemical Society. All rights reserved.

引用

页码：2746 / 2754

页数：9

共 35 条

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