CRYSTAL AND MOLECULAR-STRUCTURE OF [CU(5'-INOSINE MONOPHOSPHATE)(DIPYRIDYLAMINE)(H2O)]2.4H2O

被引：17

作者：

GELLERT, RW ^{[1
]}

FISCHER, BE ^{[1
]}

BAU, R ^{[1
]}

机构：

[1] UNIV SO CALIF,DEPT CHEM,LOS ANGELES,CA 90007

来源：

BIOCHEMICAL AND BIOPHYSICAL RESEARCH COMMUNICATIONS | 1979年 / 88卷 / 04期

关键词：

D O I：

10.1016/0006-291X(79)91141-0

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The ternary complex [Cu(5′-IMP)(dpa)(H2O)]2 has been prepared and its structure analyzed by x-ray diffraction. It has a dimeric structure in which the 5′-IMP ligands coordinate solely through their phosphate groups. This geometry is in marked contrast to that of another Cu 5′-IMP ternary complex, [Cu(5′-IMPH)(bipy)(H2O)2]+, which shows metal binding through the purine base rather than the phosphate group. © 1979.

引用

收藏

页码：1443 / 1448

页数：6

相关论文

共 16 条

[1] X-RAY EVIDENCE FOR METAL-ION BRIDGED INTRAMOLECULAR AND INTER-MOLECULAR STACKING INTERACTIONS BETWEEN NUCLEOTIDE BASES AND AROMATIC HETEROCYCLIC RINGS WITHIN TERNARY COMPLEX "[CU(5'-AMP)(BPY)(H2O)]2.(NO3)2.6H2O [J].

AOKI, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (22) :7106-7108

[2]

AOKI K, 1977, CHEM COMMUN, P600

[3]

AOKI K, UNPUBLISHED

[4] COORDINATION SITES IN NUCLEOTIDES - X-RAY CRYSTAL-STRUCTURE OF TERNARY COMPLEX COPPER(II)-URIDINE 5'-MONOPHOSPHATE-2,2'-DIPYRIDYLAMINE [J].

FISCHER, BE ;

BAU, R .

INORGANIC CHEMISTRY, 1978, 17 (01) :27-34

[5]

FISCHER BE, 1977, CHEM COMM, P272

[6]

GELLERT RW, 1979, MET IONS BIOL SYST, V8, P1

[7] TERNARY COMPLEXES IN SOLUTION .28. ENHANCED STABILITY OF TERNARY METAL ION-ADENOSINE 5'-TRIPHOSPHATE COMPLEXES - COOPERATIVE EFFECTS CAUSED BY STACKING INTERACTIONS IN COMPLEXES CONTAINING ADENOSINE-TRIPHOSPHATE, PHENANTHROLINE, AND MAGNESIUM, CALCIUM, OR ZINC IONS [J].

MITCHELL, PR ;

SIGEL, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (05) :1564-1570

[8] TERNARY COMPLEXES IN SOLUTION .18. STABILITY ENHANCEMENT OF NUCLEOTIDE-CONTAINING CHARGE-TRANSFER ADDUCTS THROUGH FORMATION OF A METAL-ION BRIDGE [J].

NAUMANN, CF ;

SIGEL, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (09) :2750-2756

[9] STEREOCHEMISTRY OF NUCLEIC ACIDS AND THEIR CONSTITUENTS .V. CRYSTAL AND MOLECULAR STRUCTURE OF A HYDRATED MONOSODIUM INOSINE 5'-PHOSPHATE . A COMMONLY OCCURRING UNUSUAL NUCLEOTIDE IN ANTICODONS OF TRNA [J].

RAO, ST ;

SUNDARALINGAM, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (05) :1210-+

[10] TERNARY CU2+ COMPLEXES - STABILITY, STRUCTURE, AND REACTIVITY [J].

SIGEL, H .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1975, 14 (06) :394-402