A NOVEL AND CONVENIENT METHOD FOR TRIFLUOROMETHYLATION OF ORGANIC HALIDES USING CF3SIR3/KF/CU(I) SYSTEM

被引：220

作者：

URATA, H ^{[1
]}

FUCHIKAMI, T ^{[1
]}

机构：

[1] SAGAMI CHEM RES CTR,4-4-1 NISHI OHNUMA,SAGAMIHARA,KANAGAWA 229,JAPAN

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 01期

关键词：

D O I：

10.1016/S0040-4039(00)71226-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Fluoride ion induced cross-coupling reaction of organic halides with trifluoromethyltrialkylsilanes takes place in the presence of Cu(I) salts under mild reaction conditions to give the corresponding trifluoromethylated products in high yields.

引用

页码：91 / 94

页数：4

共 20 条

[1] BANKS RE, 1979, ORGANOFLUORINE COMPO
[2] A REMARKABLY SIMPLE PREPARATION OF (TRIFLUOROMETHYL)CADMIUM AND (TRIFLUOROMETHYL) ZINC REAGENTS DIRECTLY FROM DIFLUORODIHALOMETHANES
BURTON, DJ
WIEMERS, DM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (17) : 5014 - 5015
[3] METHYL FLUOROSULFONYLDIFLUOROACETATE - A NEW TRIFLUOROMETHYLATING AGENT
CHEN, QY
WU, SW
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (11) : 705 - 706
[4] CROSS-COUPLING OF ORGANOSILANES WITH ORGANIC HALIDES MEDIATED BY PALLADIUM CATALYST AND TRIS(DIETHYLAMINO)SULFONIUM DIFLUOROTRIMETHYLSILICATE
HATANAKA, Y
HIYAMA, T
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (04) : 918 - 920
[5] KOBAYASHI Y, 1969, TETRAHEDRON LETT, P4095
[6] KOBAYASHI Y, 1970, CHEM PHARM BULL, V18, P2334
[7] STUDIES ON ORGANIC FLUORINE-COMPOUNDS .27. ABNORMAL REACTIONS IN THE TRIFLUOROMETHYLATION OF AROMATIC-COMPOUNDS WITH TRIFLUOROMETHYL IODIDE AND COPPER-POWDER
KOBAYASHI, Y
KUMADAKI, I
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1980, (03): : 661 - 664
[8] KOBAYASHI Y, 1979, TETRAHEDRON LETT, P4071
[9] KOBAYASHI Y, 1977, CHEM PHARM BULL, V25, P3009
[10] KOBAYASHI Y, 1972, CHEM PHARM BULL, V20, P1839

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