THE DEGENERATE ELECTRON EXCHANGE BETWEEN N,N-DIMETHYLANILINES AND THEIR RADICAL CATIONS .1. FLASH CIDNP MEASUREMENTS OF ACTIVATION PARAMETERS

被引：19

作者：

GOEZ, M

机构：

[1] Institut für Physikalische und Theoretische Chemie, Technische Universitât Braunschweig, D-3300 Braunschweig

来源：

ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE NEUE FOLGE | 1990年 / 169卷

关键词：

D O I：

10.1524/zpch.1990.169.Part_2.123

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The degenerate electron exchange between several para-substituted N,N-dimethylanilines and their corresponding radical cations in acetonitrile-d3 has been investigated by time resolved measurements of chemically induced dynamic nuclear polarization ("flash CIDNP"). The activation parameters for these processes have been determined. A linear correlation between DELTA-H] and DELTA-S] was found.

引用

页码：123 / 132

页数：10

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