RUTHENIUM AND NICKEL-COMPLEXES OF A PI-CONJUGATED ELECTRICALLY CONDUCTING POLYMER CHELATE LIGAND, POLY(2,2-BIPYRIDINE-5,5'-DIYL), AND THEIR CHEMICAL AND CATALYTIC REACTIVITY

被引：63

作者：

YAMAMOTO, T

YONEDA, Y

MARUYAMA, T

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 22期

关键词：

D O I：

10.1039/c39920001652

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Poly(2,2'-bipyridine-5,5'-diyl) (PBpy), a pi-conjugated electrically conducting chelate polymer forms electrochemically active complexes with Ru and Ni; a cyclic voltammogram of the Ru-complex shows redox peaks which are accounted for by assuming electron exchange between the Ru species through the polymer backbone, and a RuCl3-PBpy system serves as an excellent catalyst for photoevolution of hydrogen in an aqueous medium.

引用

页码：1652 / 1654

页数：3

共 20 条

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