TETRAMETHYLGUANIDINIUM AZIDE AS A NEW REAGENT FOR THE STEREOSELECTIVE SYNTHESIS OF GLYCOSYL AZIDES

被引：28

作者：

LI, C ^{[1
]}

ARASAPPAN, A ^{[1
]}

FUCHS, PL ^{[1
]}

机构：

[1] PURDUE UNIV,DEPT CHEM,W LAFAYETTE,IN 47907

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 22期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0040-4039(00)73629-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Tetramethylguanidinium azide was used in the quantitative conversion of glycosyl halides 1 - 6 to the corresponding glycosyl azides 7 - 12. The stereoselective reactions occurred with complete inversion at the anomeric centers.

引用

页码：3535 / 3538

页数：4

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