A NEW DEGRADATION OF INDOLE ALKALOID KOPSIN . CHEMICAL CORRELATION OF ALKALOIDS OF KOPSIN AND PLEIOCARPIN TYPE WITH MINOVINCIN

被引：25

作者：

GUGGISBERG, A

GORMAN, AA

BYCROFT, BW

SCHMID, H

机构：

[1] Organisch-chemisches Institut, Universität Zürich

来源：

HELVETICA CHIMICA ACTA | 1969年 / 52卷 / 01期

关键词：

D O I：

10.1002/hlca.19690520108

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new chemical degradation of (–)‐kopsine is described which completely confirms the structure of this alkaloid. Correlation of (–)‐aspidofractinine, (–)‐pleiocarpine and (–)‐kopsine with (–)‐minovincine establishes the absolute stereochemistry of these bases. It appears that, in contrast to the aspidospermine group, all alkaloids containing the aspidofractinine skeleton possess the same absolute stereochemistry. Copyright © 1969 Verlag GmbH & Co. KGaA, Weinheim

引用

页码：76 / +

页数：1

共 33 条

[1] ACHENBACH H, 1965, TETRAHEDRON LETT, P3239
[2] 10,22-DIOXOKOPSANE NA-METHYL-10,22-DIOXOKOPSANE AND NA-CARBOMETHOXY-10,22-DIOXOKOPSANE . 3 NEW ALKALOIDS OF PLEIOCARPA MUTICA BENTH
ACHENBACH, H
BIEMANN, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1965, 87 (21) : 4944 - +
[3] WEITERE ALKALOIDE AUS DEN BLATTERN VON PLEIOCARPA TUBICINA - UMWANDLUNG VON (-)-QUEBRACHAMIN IN )+)-1,2-DEHYDROASPIDOSPERMIDIN
BYCROFT, BW
PATEL, MB
SCHMID, H
SCHUMANN, D
[J]. HELVETICA CHIMICA ACTA, 1964, 47 (05) : 1147 - &
[4] DETERMINATION OF ABSOLUTE CONFIGURATION OF (-)-KOPSANONE
CRAVEN, BM
GILBERT, B
LEME, LAP
[J]. CHEMICAL COMMUNICATIONS, 1968, (16) : 955 - &
[5] MASS SPECTROMETRY IN STRUCTURAL AND STEREOCHEMICAL PROBLEMS .5. REFRACTINE AND ASPIDOFRACTINE
DJERASSI, C
LODISH, HF
FINCH, N
BUDZIKIEWICZ, H
GEORGE, T
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1962, 84 (08) : 1499 - &
[6] ALKALOID STUDIES - STRUCTURE OF ASPIDOFILINE
DJERASSI, C
ANTONACCIO, LD
FERREIRA, JM
OWELLEN, RJ
[J]. EXPERIENTIA, 1962, 18 (09): : 397 - &
[7] DIE MASSENSPEKTREN VON ALKALOIDEN DER REFRACTIN-PLEIOCARPIN-KLASSE UND DIE STRUKTUR VON ASPIDOFRACTININ, EINEM NEBENALKALOID AUS ASPIDOSPERMA REFRACTUM MART
DJERASSI, C
SCHMID, H
KUMP, WG
BATTERSBY, AR
WILSON, JM
OWELLEN, RJ
LECOUNT, DJ
BUDZIKIEWICZ, H
[J]. HELVETICA CHIMICA ACTA, 1963, 46 (03) : 742 - &
[8] 4 HEPTACYCLIC ALKALOIDS FROM ASPIDOSPERMA SPECIES
FILHO, JMF
GILBERT, B
KITAGAWA, M
LEME, LAP
DURHAM, LJ
[J]. JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC, 1966, (14): : 1260 - &
[9] GILBERT B, 1962, TETRAHEDRON LETT, P59
[10] ALKALOID STUDIES .L. ALKALOIDS OF 12 ASPIDOSPERMA SPECIES
GILBERT, B
DUARTE, AP
NAKAGAWA, Y
JOULE, JA
FLORES, SE
BRISSOLE.JA
CAMPELLO, J
CARRAZZO.EP
OWELLEN, RJ
BLOSSEY, EC
BROWN, KS
DJERASSI, C
[J]. TETRAHEDRON, 1965, 21 (05) : 1141 - +

← 1 2 3 4 →