PHASE-TRANSITIONS IN (CH3NH3)3BI2I9 (MAIB)

被引:82
作者
JAKUBAS, R
ZALESKI, J
SOBCZYK, L
机构
[1] Institute of Chemistry, University of Wroclaw
关键词
D O I
10.1080/00150199008018741
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Crystals of tris (methylammonium) nonaiododibismuthate were grown which turned out to be isomorphous with Cs3Bi2I9 and (CH3NH3)3Sb2I9. Two phase transitions, at 223 (second order) and 142 K (first order), were revealed. The low temperature phase transition is characterized by a strong dielectric anomaly. The pyroelectric behaviour could indicate a ferrielectric ordering below 142 K. © 1990, Taylor & Francis Group, LLC. All rights reserved.
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页码:109 / 114
页数:6
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