GALLANE ARSINE, H3GA.ASH3 - PREDICTION OF A STABLE GA AS BONDED SPECIES

被引：26

作者：

DOBBS, KD

TRACHTMAN, M

BOCK, CW

COWLEY, AH

机构：

[1] UNIV DELAWARE,DEPT CHEM & BIOCHEM,NEWARK,DE 19716

[2] PHILADELPHIA COLL TEXT & SCI,DEPT CHEM,PHILADELPHIA,PA 19144

[3] UNIV TEXAS,DEPT CHEM,AUSTIN,TX 78712

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1990年 / 94卷 / 13期

关键词：

D O I：

10.1021/j100376a006

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The structure, harmonic frequencies, and binding energy of the simplest gallane-arsine molecular adducts have been calculated with ab initio molecular orbital methods. H3Ga·AsH3 is predicted to have a binding energy of 16 kcal mol-1 (MP4/ HUZSP**//RHF/HUZSP*) and should be observable in the gas phase. © 1990 American Chemical Society.

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页码：5210 / 5211

页数：2

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