XPS SPECTRA OF COPPER AND NICKEL BIURET COMPLEXES - OBSERVATIONS OF INTENSE SATELLITE STRUCTURE IN THE 2P SPECTRUM OF A COPPER(III) SYSTEM

被引:23
作者
BROWN, DG [1 ]
WESER, U [1 ]
机构
[1] UNIV TUBINGEN,INST ANORGAN BIOCHEM PHYSIOL CHEM,D-7400 TUBINGEN 1,FED REP GER
来源
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1979年 / 34卷 / 07期
关键词
D O I
10.1515/znb-1979-0721
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A series of copper and nickel biuret complexes has been studied b y X-ray photoelectron spectroscopy (XPS). The results include one of the first reports of the XPS spectrum of a copper(III) complex. Significantly, this diamagnetic complex exhibits intense satellite structure in both the Cu 2P3/2 and Cu 2P1/2 regions. The isoelectronic nickel(II) complex shows no comparable satellite structure. © 1979, Walter de Gruyter. All rights reserved.
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页码:989 / 994
页数:6
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