MICHAEL ADDITION OF NITROALKANES TO DIMETHYL MALEATE WITH DBU - A NEW DIRECT METHOD FOR THE SYNTHESIS OF POLYFUNCTIONALIZED ALPHA,BETA-UNSATURATED ESTERS

被引：48

作者：

BALLINI, R

RINALDI, A

机构：

[1] Dipartimento di Scienze Chimiche dell'Università, I-62032 Camerino

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 49期

关键词：

D O I：

10.1016/0040-4039(94)88479-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Michael addition of nitroalkanes to dimethyl maleate, in acetonitrile and with 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) as base affords, directly, polyfunctionalized alpha,beta-unsaturated esters, via elimination of nitrous acid.

引用

页码：9247 / 9250

页数：4

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