SYNTHESIS, PHYSICAL CHARACTERIZATIONS, AND LANGMUIR FILMS OF NEW METHANOFULLERENES

被引：42

作者：

RAVAINE, S

LEPECQ, F

MINGOTAUD, C

DELHAES, P

HUMMELEN, JC

WUDL, F

PATTERSON, LK

机构：

[1] CTR RECH PAUL PASCAL,CNRS,F-33600 PESSAC,FRANCE

[2] UNIV CALIF SANTA BARBARA,INST POLYMERS & ORGAN SOLIDS,SANTA BARBARA,CA 93106

[3] UNIV NOTRE DAME,RADIAT LAB,NOTRE DAME,IN 46556

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1995年 / 99卷 / 23期

关键词：

D O I：

10.1021/j100023a037

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Various methanofullerenes functionalized with either hydrophobic or polar groups have been synthesized. Studies of such compounds by surface pressure measurements and in situ UV-visible spectroscopy in Langmuir films show that these two types of functionalizations do not prevent the formation of aggregates at the nitrogen-water interface. Except for one compound studied in the present work, it appears that the aggregation occurs as soon as the spreading of the fullerenes solutions. However, the aggregates obtained appear to have different characteristics than those obtained with pure C-60.

引用

页码：9551 / 9557

页数：7

共 26 条

[1] C60 IN MODEL BIOLOGICAL-SYSTEMS - A VISIBLE-UV ABSORPTION STUDY OF SOLVENT-DEPENDENT PARAMETERS AND SOLUTE AGGREGATION [J].