PRODUCTS OF METABOLISM OF MICROORGANISM .67. STRUCTURE OF GRANATICIN AND GRANATICIN B .2. CRYSTAL STRUCTURE OF TRI-O-ACETYL-O-IODOACETYLGRANATICIN

被引：36

作者：

BRUFANI, M

DOBLER, M

机构：

[1] Organisch-chemisches Laboratorium, idg Techn Hochschule Zürich

来源：

HELVETICA CHIMICA ACTA | 1968年 / 51卷 / 06期

关键词：

D O I：

10.1002/hlca.19680510610

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structure of tri‐O‐acetyl‐O‐iodoacetyl‐granaticin has been determined by X‐ray analysis of threedimensional diffractometer intensity data. The crystals are orthorhombic, a = 17.85, b = 14.90, c = 11.26 Å, Z = 4, space group P212121. The molecular structure was established by the heavy atom method and refined by full‐matrix least‐squares analysis. The molecular constitution and configuration is given by formula II. The chirality was determined by the use of anomalous dispersion effects. Copyright © 1968 Verlag GmbH & Co. KGaA, Weinheim

引用

页码：1269 / &

共 9 条

[1]

BIJVOET JM, 1955, ENDEAVOUR, V14, P71

[2] BICYCLO[2,2,2]OCTANE CONFORMATION - X-RAY ANALYSIS OF 1-P-BROMOBENZENESULPHONYLOXYMETHYLBICYCLO[2,2,2]OCTANE [J].