ORGANOLANTHANIDE(II) CHEMISTRY - REACTIONS OF CP-STAR-2SM(THF)2 WITH 1,4-DIAZADIENES AND CYCLOOCTATETRAENE

被引：65

作者：

RECKNAGEL, A ^{[1
]}

NOLTEMEYER, M ^{[1
]}

EDELMANN, FT ^{[1
]}

机构：

[1] UNIV GOTTINGEN,INST ANORGAN CHEM,TAMMANNSTR 4,W-3400 GOTTINGEN,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 410卷 / 01期

关键词：

D O I：

10.1016/0022-328X(91)83024-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cp*2Sm(THF)2 reacts with 1,4-diazadienes (DAD) to give 1:1-adducts of the type Cp*2Sm(DAD). The molecular structure of Cp*2Sm(tBuN = CHCH = NtBu) (2) has been determined by X-ray crystallography. These complexes can be described as Cp*2Sm(III) derivatives of the diazadiene radical anions as indicated by spectroscopic and structural data. Treatment of Cp*2Sm(THF)2 with 2-pyridinealdazine yields the binuclear complex (mu-C12H10N4)[Cp*2Sm]2 (5). Cyclooctatetraene reacts with Cp*2Sm(THF)2 to give the known compound Cp*Sm(COT)(TNF) (6).

引用

页码：53 / 61

页数：9

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