CHILOCORINE - HEPTACYCLIC ALKALOID FROM A COCCINELLID BEETLE

被引:35
作者
MCCORMICK, KD
ATTYGALLE, AB
XU, SC
SVATOS, A
MEINWALD, J
HOUCK, MA
BLANKESPOOR, CL
EISNER, T
机构
[1] TEXAS TECH UNIV, DEPT BIOL SCI, LUBBOCK, TX 79404 USA
[2] CORNELL UNIV, NEUROBIOL & BEHAV SECT, ITHACA, NY 14853 USA
基金
美国国家卫生研究院;
关键词
D O I
10.1016/S0040-4020(01)86955-6
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A novel heptacyclic alkaloid, for which we coin the name chilocorine, was isolated from a ladybird beetle, Chilocorus cacti. It has a unique structure made up of two tricyclic substructures, 2-methylperhydro-9b-azaphenalene and 3,4-dimethyloctahydro-8b-azaacenaphthyle The proposed structure is based on mass spectrometric, ultraviolet spectroscopic, and NMR evidence.
引用
收藏
页码:2365 / 2372
页数:8
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