ELECTROCHEMICAL INVESTIGATION ON AN ACRYLATED THIOPHENE

被引：10

作者：

HOGERVORST, ACR

KOCK, TJJM

DERUITER, B

VANDERWAAL, A

机构：

[1] TNO Plastics and Rubber Research Institute, NL-2600 JA Delft

来源：

SYNTHETIC METALS | 1993年 / 55卷 / 2-3期

关键词：

CONDUCTING POLYMER; ELECTRON BEAM IRRADIATION; CROSS-LINKING; ELECTROCHEMISTRY; POLY(2-(3-THIENYL)ETHYL ACRYLATE); POLYTHIOPHENE; POLY(3-N-DECYLTHIOPHENE);

D O I：

10.1016/0379-6779(93)90299-C

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The electrochemical behaviour of electropolymerized 2-(3-thienyl)ethyl acrylate (PAcrT) has been investigated, and compared to the behaviour of electropolymerized thiophene and 3-n-decylthiophene (PDT). The effect of electron beam irradiation on the electrochemical properties of these three polymers has been studied. It has been found that for PAcrT the oxidation wave shifts to higher potentials upon electron beam irradiation. For PDT a similar but smaller change occurs. We suggest that the shift of the oxidation wave of PAcrT is caused by cross-links, formed between the acrylate substituents, which fixate the main chain parts in twisted states and reduce the conjugation length.

引用

页码：1644 / 1649

页数：6

共 7 条

[1]

CAI SX, 1991, J MOL ELECTRON, V7, P63

[2]

KRISCHE B, 1989, SYNTHETIC MET, V28, pC263

[3] THE INFLUENCE OF WATER ON THE CYCLING BEHAVIOR OF THE POLYPYRROLE ELECTRODE IN LITHIUM CELLS [J].