MODIFICATION OF THE SURFACE-COMPOSITION OF MOLYBDENUM OXYNITRIDE DURING HYDROCARBON CATALYSIS

被引:37
作者
DJEGAMARIADASSOU, G [1 ]
BOUDART, M [1 ]
BUGLI, G [1 ]
SAYAG, C [1 ]
机构
[1] STANFORD UNIV,DEPT CHEM ENGN,STANFORD,CA 94305
关键词
MOLYBDENUM; OXYNITRIDE; CARBURIZATION; HYDROGENATION; ACTIVATION;
D O I
10.1007/BF00808605
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
With an oxygen containing molybdenum nitride catalyst, the rate of hydrogenation of propylbenzene increases with time. This is attributed to the carburization of surface during reaction. Both surface reactivity in chemisorption and superficial chemical composition change during the activation of the catalyst.
引用
收藏
页码:411 / 420
页数:10
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