STRUCTURE OF DONOR-ACCEPTOR COMPLEXES .X. COMPLEXES OF CYANOACETAMIDE WITH LEWIS ACIDS

被引:18
作者
PAUL, RC
CHADHA, SL
机构
[1] Department of Chemistry, Panjab University, Chandigarh
关键词
D O I
10.1071/CH9691381
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Complexes of cyanoacetamide with aluminium chloride and bromide, anti- mony(V) chloride, boron(III) bromide, tin(IV) chloride and bromide, titanium(IV) chloride and bromide, and zirconium(IV) chloride have been prepared. The molar conductances of the complexes in nitrobenzene indicate their non-ionic nature. The infrared spectra indicate bonding of the metal halides to the carbonyl oxygen atom of the ligand. Metal- to-oxygen bonding also gets support from the far-infrared spectral data. © 1969, CSIRO. All rights reserved.
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页码:1381 / &
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