SYNTHESIS OF ETHYNYLPHOSPHONATE ESTERS . A NOVEL ORGANOSILICON REARRANGEMENT

被引：23

作者：

BURT, DW

SIMPSON, P

机构：

[1] School of Molecular Sciences, University of Sussex, Brighton

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 17期

关键词：

D O I：

10.1039/j39690002273

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The synthesis of ethynylphosphonate esters in high yield is described. Di-isopropyl trimethylsilylethynylphosphonate, an intermediate in the synthesis of the di-isopropyl ester, undergoes a novel thermal rearrangement with loss of propene and migration of silicon from carbon to oxygen.

引用

页码：2273 / &

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