APPLICATION OF 2-DIMENSIONAL NMR-SPECTROSCOPY IN THE STRUCTURAL DETERMINATION OF MARINE NATURAL-PRODUCTS - TOTAL STRUCTURAL ASSIGNMENT OF THE CEMBRANOID DITERPENE EUPALMERIN ACETATE THROUGH THE USE OF 2-DIMENSIONAL H-1-H-1, H-1-C-13, AND C-13-C-13 CHEMICAL-SHIFT CORRELATION SPECTROSCOPY

被引：27

作者：

FONTAN, LA ^{[1
]}

YOSHIDA, WY ^{[1
]}

RODRIGUEZ, AD ^{[1
]}

机构：

[1] UNIV PUERTO RICO,DEPT CHEM,RIO PIEDRAS,PR 00931

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 16期

关键词：

D O I：

10.1021/jo00303a039

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Numerous cembranoid diterpenes have been isolated from terrestrial organisms (plants and insects) and especially from marine organisms of the coelenterate phylum4. © 1990, American Chemical Society. All rights reserved.

引用

页码：4956 / 4960

页数：5

共 33 条

[1] 2-DIMENSIONAL SPECTROSCOPY - APPLICATION TO NUCLEAR MAGNETIC-RESONANCE [J].

AUE, WP ;

BARTHOLDI, E ;

ERNST, RR .

JOURNAL OF CHEMICAL PHYSICS, 1976, 64 (05) :2229-2246

[2] H-1 AND C-13 ASSIGNMENTS FROM SENSITIVITY-ENHANCED DETECTION OF HETERONUCLEAR MULTIPLE-BOND CONNECTIVITY BY 2D MULTIPLE QUANTUM NMR [J].

BAX, A ;

SUMMERS, MF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (08) :2093-2094

[3] STRUCTURE ELUCIDATION OF THE ANTIBIOTIC DESERTOMYCIN THROUGH THE USE OF NEW TWO-DIMENSIONAL NMR TECHNIQUES [J].

BAX, A ;

ASZALOS, A ;

DINYA, Z ;

SUDO, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (25) :8056-8063

[4] AN NMR TECHNIQUE FOR TRACING OUT THE CARBON SKELETON OF AN ORGANIC-MOLECULE [J].

BAX, A ;

FREEMAN, R ;

FRENKIEL, TA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (08) :2102-2104

[5] AN IMPROVED METHOD FOR HETERONUCLEAR CHEMICAL-SHIFT CORRELATION BY TWO-DIMENSIONAL NMR [J].

BAX, A ;

MORRIS, GA .

JOURNAL OF MAGNETIC RESONANCE, 1981, 42 (03) :501-505

[6] OPTIMIZATION OF 2-DIMENSIONAL HOMONUCLEAR RELAYED COHERENCE TRANSFER NMR-SPECTROSCOPY [J].

BAX, A ;

DROBNY, G .

JOURNAL OF MAGNETIC RESONANCE, 1985, 61 (02) :306-320

[7] INVESTIGATION OF COMPLEX NETWORKS OF SPIN-SPIN COUPLING BY TWO-DIMENSIONAL NMR [J].

BAX, A ;

FREEMAN, R .

JOURNAL OF MAGNETIC RESONANCE, 1981, 44 (03) :542-561

[8]

Ciereszko L.S., 1973, P183

[9] DISTORTIONLESS ENHANCEMENT OF NMR SIGNALS BY POLARIZATION TRANSFER [J].

DODDRELL, DM ;

PEGG, DT ;

BENDALL, MR .

JOURNAL OF MAGNETIC RESONANCE, 1982, 48 (02) :323-327

[10] MOLECULAR-STRUCTURES AND ABSOLUTE-CONFIGURATIONS OF EUPALMERIN ACETATE AND EUPALMERIN ACETATE DIBROMIDE AT LOW-TEMPERATURE [J].

EALICK, SE ;

VANDERHELM, D ;

WEINHEIMER, AJ .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1975, 31 (JUN15) :1618-1626

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