POLYMER-CHAIN CROSS-SECTION AND MOONEY-RIVLIN CONSTANTS .2.

被引：22

作者：

BOYER, RF ^{[1
]}

MILLER, RL ^{[1
]}

机构：

[1] MIDLAND MACROMOLEC INST,MIDLAND,MI 48640

来源：

RUBBER CHEMISTRY AND TECHNOLOGY | 1977年 / 50卷 / 04期

关键词：

MATHEMATICAL TECHNIQUES - RUBBER; SYNTHETIC - Physical Properties;

D O I：

10.5254/1.3535176

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

In the reported study, the authors have started with a critical examination of published Mooney-Rivlin constants on the common commercial elastomers and some experimental ones. Following a suggestion by Treloar, plots were made of C//2/C//1 against 2C//1 in order to select values of the ratio at constant 2C//1 in comparing all elastomers. Cross-sectional areas of elastomer chains in the amorphous state were assumed to be proportional to areas for the same polymers in the crystalline state. A plot of log C//2/C//1 against log (area per chain) is linear with a slope of about minus 2. This is the first positive correlation of Mooney-Rivlin constants with a specific molecular parameter. Additional reports on the comprehensive studies are presented in six appendixes.

引用

页码：798 / 818

页数：21