REACTION OF ETHYLPEROXY RADICALS WITH NO2

被引：18

作者：

ADACHI, H

BASCO, N

机构：

[1] Department of Chemistry, University of British Columbia, Vancouver

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 67卷 / 2-3期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1016/0009-2614(79)85171-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The rate constant for the reaction C2H5O2+NO2 - products (10) has been measured directly by flash photolysis and kinetic spectroscopy in the pressure range 44-676 Torr. At room temperature k10=(7.5 ± 0.4) × 103 mole-1 s-1 so that the rate of formation of the probable primary product, peroxyethyl nitrate [(C2H5O2NO2) may be significant in urban atmospheres. © 1979.

引用

页码：324 / 328

页数：5

共 24 条

[1] KINETIC SPECTROSCOPY STUDY OF THE REACTION OF CH3O2 WITH NO
ADACHI, H
BASCO, N
[J]. CHEMICAL PHYSICS LETTERS, 1979, 63 (03) : 490 - 492
[2] KINETIC SPECTROSCOPY STUDY OF THE REACTION OF C2H5O2 WITH NO
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BASCO, N
[J]. CHEMICAL PHYSICS LETTERS, 1979, 64 (03) : 431 - 434
[3] ADACHI H, UNPUBLISHED
[4] FLASH-PHOTOLYSIS STUDY OF SPECTRA OF CH3O2 AND C(CH3)3O2 RADICALS AND KINETICS OF THEIR MUTUAL REACTIONS AND WITH NO
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[5] RATES OF REACTION OF HO2 WITH HO AND O STUDIED BY LASER MAGNETIC-RESONANCE
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[6] COMPUTER MODELING OF SMOG CHAMBER DATA - PROGRESS IN VALIDATION OF A DETAILED MECHANISM FOR THE PHOTO-OXIDATION OF PROPENE AND NORMAL-BUTANE IN PHOTO-CHEMICAL SMOG
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[J]. INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1979, 11 (01) : 45 - 101
[7] PHOTOOXIDATION OF METHANE IN PRESENCE OF NO AND NO2
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KERR, JA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1976, 72 : 2044 - 2060
[8] KINETICS OF REACTION OF HO2 WITH NITRIC-OXIDE AND NITROGEN-DIOXIDE
COX, RA
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[J]. JOURNAL OF PHOTOCHEMISTRY, 1975, 4 (1-2): : 139 - 153
[9] SIGNIFICANCE OF PEROXYNITRIC ACID IN ATMOSPHERIC CHEMISTRY OF NITROGEN-OXIDES
COX, RA
DERWENT, RG
HUTTON, AJL
[J]. NATURE, 1977, 270 (5635) : 328 - 329
[10] PHOTOLYSIS OF NITROUS-ACID IN PRESENCE OF ACETALDEHYDE
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KERR, JA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1976, 72 : 2061 - 2075

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